Benzyl N′-(1-methyl-1H-indol-3-ylmethylidene)hydrazinecarbodithioate
نویسندگان
چکیده
The N'-(1-methyl-1H-indol-3-ylmethyl-idene)hydrazine-carbo-dithio-ate portion of the title mol-ecule, C(18)H(17)N(3)S(2), is nearly planar; this unit and the phenyl ring subtend an angle of 112.9 (2)° at the methyl-ene C atom.
منابع مشابه
Benzyl N′-(1-methyl-1H-indol-2-ylmethylene)hydrazinecarbodithioate
In the title compound, C(18)H(17)N(3)S(2), the dihedral angle between the planes of the aromatic ring systems is 83.63 (16)°. In the crystal structure, inversion dimers occur, linked by pairs of N-H⋯S hydrogen bonds.
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The C(10)H(8)N(3)S(2) portion of the title mol-ecule, C(17)H(15)N(3)S(3), is nearly planar (r.m.s. deviation 0.05 Å); this unit and the phenyl ring subtend an angle of 114.5 (2)° at the methyl-ene C atom.
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In the crystal of the title compound, C(17)H(15)N(3)S(2)·0.5C(2)H(6)O, the mol-ecules are linked by a pair of N-H(aliphatic)⋯S hydrogen bonds across a center of inversion, forming a dimer. The ethanol solvent mol-ecule, which is statistically disordered about a crystallographic twofold rotation axis, accepts an N-H(aromatic)⋯O hydrogen bond; the hydr-oxy group of the solvent mol-ecule is not en...
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